Palladium(0)-catalyzed amination of allylic natural terpenic functionalized olefins-Reference-Cited by-同舟云学术

Palladium(0)-catalyzed amination of allylic natural terpenic functionalized olefins

Published:2008-09-01 Issue:3 Volume:6 Page:470-476
ISSN:2391-5420
Container-title:Open Chemistry
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Author:

Houssame Soufiane¹,Anane Hafid²,Firdoussi Larbi¹,Karim Abdellah¹

Affiliation:

1. 1Laboratoire de Chimie de Coordination, Faculté des Sciences-Semlalia, Université Cadi Ayyad, BP 2390, Marrakech, Morocco

2. 2Département Sciences de la matière, Faculté Polydisciplinaire de Safi, Route Sidi bouzid, B.P 4162, Safi Université Cadi Ayyad, Morocco

Abstract

AbstractThe palladium(0) catalyzed amination of allylic acetates and carbonates derivatives from terpenic olefins was carried out under mild conditions. The reaction offers a very good method for the preparation of allylic amines and thus to provide a useful entry to new functionalized terpenic olefin products. The mechanism involving a formation of p-allyl-palladium intermediate complex is in good agreement with the results obtained with the optically active substrates, as well as via an analysis of the observed regio-and stereoselectivity.

Publisher

Walter de Gruyter GmbH

Subject

Materials Chemistry,General Chemistry

Link

http://link.springer.com/content/pdf/10.2478/s11532-008-0042-3.pdf

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