Sensitive Absorption Methods for Quantitative Gas Phase Kinetic Measurements. Part 1: Frequency Modulation Spectroscopy

Abstract

Frequency modulation spectroscopy (FMS) and cavity ringdown spectroscopy (CRDS) are sensitive absorption based detection methods that have found widespread applications in gas phase reaction kinetics. In part 1 of this review, the theoretical foundations of FMS are addressed with a special emphasis on time-resolved quantitative measurements of concentration profiles. A complementary review of CRDS can be found in part 2 (Z. Phys. Chem. 222 (2008) 31–61). Practical aspects, possible pitfalls, attainable sensitivities, and modern trends are discussed. Kinetic studies based on FMS measurements as a time-resolved detection tool are briefly reviewed and a bibliography with more than a hundred entries is included to facilitate the access to the large body of original literature.