Unusual Transformations of Cyclic Allenes with an Enamine Moiety into Complex Frameworks-Reference-Cited by-同舟云学术

Unusual Transformations of Cyclic Allenes with an Enamine Moiety into Complex Frameworks

Published:2020-02-04 Issue:07 Volume:31 Page:672-676
ISSN:0936-5214
Container-title:Synlett
language:en
Short-container-title:Synlett

Author:

Titov Alexander A.¹^ORCID,Kobzev Maxim S.¹,Borisova Tatiana N.¹,Sorokina Elena A.¹,Van der Eycken Erik¹²,Varlamov Alexey V.¹,Voskressensky Leonid G.¹

Affiliation:

1. Organic Chemistry Department, Peoples’ Friendship University of Russia (RUDN University)

2. Laboratory for Organic and Microwave-Assisted Chemistry (LOMAC), Department of Chemistry, University of Leuven (KU Leuven)

Abstract

The thermolysis reactions of benzoazacyclodecatrienes under microwave irradiation conditions in toluene at 150 °C afforded complex azabenzo[a]cyclopropa[cd]azulene and (epiminomethano)cyclopenta[a]indene frameworks. Cyclopropanes were established as intermediates of the ultimate thermolysis products.

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0039-1691586.pdf

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