Switchable light vs. acid-induced transformations of complex framework compounds at room temperature

Author:

Kobzev Maxim S.1,Titov Alexander A.1,Borisova Tatiana N.1,Voskressensky Leonid G.1,Varlamov Alexey V.1,D'Alterio Massimo Christian2ORCID,Petrone Alessio23ORCID,Luque Rafael4ORCID,Talarico Giovanni23ORCID

Affiliation:

1. Organic Chemistry Department, Peoples’ Friendship University of Russia (RUDN University), 6 Miklukho-Maklaya St, Moscow, 117198, Russian Federation

2. Department of Chemical Sciences, Università degli Studi di Napoli Federico II, via Cintia, 80126 Napoli, Italy

3. Scuola Superiore Meridionale, Largo San Marcellino 10, I-80138, Napoli, Italy

4. Departamento de Quimica Organica, Universidad de Cordoba, Campus de Rabanales, Edificio Marie Curie (C-3), Ctra Nnal IV-A, Km 396, Cordoba, Spain

Abstract

A novel protocol for the synthesis of complex framework compounds containing a VCP fragment is presented by means of UV conversion of CP derivatives at r.t., providing high yields of target products in an unprecedented atom economical reversible step.

Funder

Ministero dell’Istruzione, dell’Università e della Ricerca

RUDN University

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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