Dehydrogenative Allylic Aminations of But-3-enoic Acid Derivatives-Reference-Cited by-同舟云学术

Dehydrogenative Allylic Aminations of But-3-enoic Acid Derivatives

Published:2016-07-22 Issue:19 Volume:48 Page:3400-3412
ISSN:0039-7881
Container-title:Synthesis
language:en
Short-container-title:Synthesis

Author:

Diamante Daria¹,Gabrieli Sara¹,Benincori Tiziana²,Broggini Gianluigi²,Oble Julie¹,Poli Giovanni¹

Affiliation:

1. Sorbonne Universités, UPMC Univ Paris 06, Institut Parisien de Chimie Moléculaire, UMR CNRS 8232

2. Dipartimento di Scienza e Alta Tecnologia, Università degli Studi dell’Insubria

Abstract

Two complementary Pd-catalyzed protocols enabling the γ-selective intermolecular allylic amination of but-3-enoic acid derivatives are reported. These transformations can be successfully achieved via either a direct Pd(II)-catalyzed protocol or by way of a one-pot Pd(II)/Pd(0)-catalyzed sequence, depending on the nature of the nitrogen nucleophile used.

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry,Catalysis

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0035-1562453.pdf

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