Allylsulfones through Palladium‐Catalyzed Allylic C−H Sulfonylation of Terminal Alkenes-Reference-Cited by-同舟云学术

Allylsulfones through Palladium‐Catalyzed Allylic C−H Sulfonylation of Terminal Alkenes

Published:2023-01-26 Issue:8 Volume:26 Page:
ISSN:1434-193X
Container-title:European Journal of Organic Chemistry
language:en
Short-container-title:Eur J Org Chem

Author:

Chen Tingting¹,Lahbi Jassmin¹²,Broggini Gianluigi²^ORCID,Pradal Alexandre¹^ORCID,Poli Giovanni¹^ORCID

Affiliation:

1. Sorbonne Université Faculté des Sciences et Ingénierie, CNRS Institut Parisien de Chimie Moléculaire, IPCM 4 place Jussieu 75005 Paris France

2. Dipartimento di Scienza e Alta Tecnologia Università dell'Insubria via Valleggio 11 22100 Como Italy

Abstract

AbstractTwo previously unknown protocols for Pd‐catalyzed allylic C−H sulfonylation of terminal alkenes have been developed. While the former consists of a direct Pd(II)‐catalyzed oxidative C−H allylic sulfonylation in the presence of sulfinate anions, the latter involves a sequential one‐pot Pd(II)‐catalyzed C−H allylic acetoxylation followed by a Pd(0)‐catalyzed sulfonylation. The scope of both protocols was studied on 25 examples.

Funder

China Scholarship Council

Publisher

Wiley

Subject

Organic Chemistry,Physical and Theoretical Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/ejoc.202201493

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