Affiliation:
1. Department of Chemistry, Humboldt-Universität zu Berlin
Abstract
In this account we describe studies on the reactivity of rhodium(I) complexes of the type [Rh(E)(PEt3)3], where E represents hydrido, fluorido, germyl, boryl or silyl ligands, towards fluorinated olefins. The results are compared with those reported by other research groups on fluoroolefins, as well as with the chemistry of compounds [Rh(E)(PEt3)3] towards fluoroaromatics in terms of selectivity and mechanisms.1 Introduction2 Reactivity Towards Fluoroolefins2.1 Reactivity of Hexafluoropropene2.2 Reactivity of (E)-1,2,3,3,3-Pentafluoropropene2.3 Reactivity of 2,3,3,3-Tetrafluoropropene and (E)-1,3,3,3-Tetrafluoropropene2.4 Reactivity of 3,3,3-Trifluoropropene2.5 Reactivity of Pentafluorostyrene3 Conclusion and Perspective
Funder
Deutsche Forschungsgemeinschaft
Cited by
13 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献