C–H and C–F bond activation of fluorinated propenes at Rh: enabling cross-coupling reactions with outer-sphere C

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C–H and C–F bond activation of fluorinated propenes at Rh: enabling cross-coupling reactions with outer-sphere C–C coupling

Published:2024 Issue:22 Volume:15 Page:8472-8477
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Talavera Maria¹²^ORCID,Mollasalehi Soodeh²^ORCID,Braun Thomas²^ORCID

Affiliation:

1. Facultad de Química, Universidade de Vigo, Campus Universitario, 36310 Vigo, Spain

2. Department of Chemistry, Humboldt Universität zu Berlin, Brook-Taylor Straße 2, 12489 Berlin, Germany

Abstract

Cross coupling reactions of fluorinated olefins occur by C–H bond activation at Rh to provide a fluorinated ligand for a subsequent outer-sphere C–F bond functionalization.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC00951G

Reference71 articles.

1. T.Hiyama , Organofluorine Compounds: Chemistry and Applications , Springer , Berlin , 2000

2. Next Generation of Fluorine-Containing Pharmaceuticals, Compounds Currently in Phase II–III Clinical Trials of Major Pharmaceutical Companies: New Structural Trends and Therapeutic Areas

3. Fluorine in medicinal chemistry

4. P.Kirsch , Modern Fluoroorganic Chemistry: Synthesis, Reactivity and Applications , Wiley-VCH , Weinheim , 2nd edn, 2013

5. A comprehensive modeling of choked two-phase flow through short-tube orifices with application to alternative refrigerants HFO-1234yf and HFO-1234ze

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