Palladium-Catalyzed [3+2] Cycloaddition of Vinylaziridine and Indane-1,3-diones: Diastereo- and Enantioselective Access to Spiro-Pyrrolidines-Reference-Cited by-同舟云学术

Palladium-Catalyzed [3+2] Cycloaddition of Vinylaziridine and Indane-1,3-diones: Diastereo- and Enantioselective Access to Spiro-Pyrrolidines

Published:2020-04-07 Issue:14 Volume:52 Page:2038-2044
ISSN:0039-7881
Container-title:Synthesis
language:en
Short-container-title:Synthesis

Author:

Vetica Fabrizio¹^ORCID,Bailey Stephen J.¹,Kumar Mukesh¹,Mahajan Suruchi¹,von Essen Carolina²,Rissanen Kari²,Enders Dieter¹

Affiliation:

1. Institute of Organic Chemistry, RWTH Aachen University

2. Department of Chemistry, Nanoscience Centre University of Jyvaskyla

Abstract

A mild and efficient palladium-catalyzed [3+2] cycloaddition of vinylaziridine and indane-1,3-diones has been realized. The resulting spiro-pyrrolidines were provided in excellent yields and, with the introduction of the leucine-derived phosphine ligand, moderate to good enantio- and diastereoselectivities.

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry,Catalysis

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0040-1707472.pdf

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