An Efficient Copper-Catalyzed C(sp2)–S Formation Starting from Aryl Iodides and Tetramethylthiuram Monosulfide (TMTM)-Reference-Cited by-同舟云学术

An Efficient Copper-Catalyzed C(sp2)–S Formation Starting from Aryl Iodides and Tetramethylthiuram Monosulfide (TMTM)

Published:2020-07-20 Issue: Volume: Page:
ISSN:0039-7881
Container-title:Synthesis
language:en
Short-container-title:Synthesis

Author:

Dong Zhi-Bing¹²³⁴^ORCID,Wu Yue-Xiao¹,Peng Kang¹,Li Jing-Hang¹

Affiliation:

1. School of Chemistry and Environmental Engineering, Wuhan Institute of Technology

2. Key Laboratory of Green Chemical Process, Ministry of Education, Wuhan Institute of Technology

3. Ministry of Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Hubei University

4. Hubei Key Laboratory of Novel Reactor and Green Chemistry Technology, Wuhan Institute of Technology

Abstract

A new, efficient copper-catalyzed C(sp2)–S formation of phenyl dithiocarbamates starting from aryl iodides and tetramethylthiuram monosulfide (TMTM) was developed. The target compounds, phenyl dithiocarbamates with active sites, were synthesized smoothly in good to excellent yields. The easy performance, high yields, decent functional group compatibility, and cost-effective substrates make the protocol practical and attractive in C–S bond formation.

Funder

Department of Science and Technology, Hubei Provincial People’s Government

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry,Catalysis

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0040-1707899.pdf

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