Copper-Promoted Hiyama Cross-Coupling of Arylsilanes With Thiuram Reagents: A Facile Synthesis of Aryl Dithiocarbamates-Reference-Cited by-同舟云学术

Copper-Promoted Hiyama Cross-Coupling of Arylsilanes With Thiuram Reagents: A Facile Synthesis of Aryl Dithiocarbamates

Published:2022-04-26 Issue: Volume:10 Page:
ISSN:2296-2646
Container-title:Frontiers in Chemistry
language:
Short-container-title:Front. Chem.

Author:

Wang Yiying,Shen Hongtao,Qiu Jianhua,Chen Mengqi,Song Weimin,Zhao Mingqin,Wang Longfei,Bai Feng,Wang Hongxia,Wu Zhiyong

Abstract

We report herein a facile Hiyama cross-coupling reaction of arylsilanes with thiuram reagents (tetraalkylthiuram disulfides or tetraalkylthiuram monosulfide) enabled by copper fluoride. Compared to our previous work, this protocol is an alternative protocol for the generation of S-aryl dithiocarbamates. It features low toxic and readily available substrates, cost-effective promoter, easy performance, and provides good yields.

Funder

Natural Science Foundation of Henan Province

Education Department of Henan Province

Henan Agricultural University

Publisher

Frontiers Media SA

Subject

General Chemistry

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