Abstract
A procedure for the α-arylation of α,α-disubstituted esters and ketones to generate quaternary carbon centers is described. The developed protocol is operationally simple and employs an air- and moisture-stable dinuclear Pd(I) complex [Pd(μ-I)(Pt-Bu3)]2 to mediate selective α-arylation of aromatic C–I/Br bonds in the presence of aromatic C–Cl and/or C–OTf sites.
Subject
Organic Chemistry,Catalysis
Cited by
14 articles.
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