α-Arylation of (hetero)aryl ketones in aqueous surfactant media-Reference-Cited by-同舟云学术

α-Arylation of (hetero)aryl ketones in aqueous surfactant media

Published:2021 Issue:13 Volume:23 Page:4858-4865
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Wood Alex B.¹²³⁴^ORCID,Roa Daniel E.¹²³⁴^ORCID,Gallou Fabrice⁵⁶⁷^ORCID,Lipshutz Bruce H.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. University of California

3. Santa Barbara

4. USA

5. Novartis Pharma AH

6. CH-4057 Basel

7. Switzerland

Abstract

α-Arylations can be run under micellar catalysis conditions using a Pd(i) pre-catalyst together with KO-t-Bu as base. Sequences using this coupling along with as many as four additional steps can be carried out in a 1-pot fashion, all in water.

Funder

National Science Foundation

Novartis

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/GC/D1GC01572A

Reference50 articles.

1. Palladium-Catalyzed α-Arylation Reactions in Total Synthesis

2. Palladium-Catalyzed Cross-Coupling Reactions: A Powerful Tool for the Synthesis of Agrochemicals

3. Accelerating Pharmaceutical Development via Metal‐Mediated Bond Formation

4. Expeditious synthesis of novel NK1 antagonists based on a 1,2,4-trisubstituted cyclohexane

5. Sequential palladium-catalysed C- and N-arylation reactions as a practical and general protocol for the synthesis of the first series of oxcarbazepine analogues

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