Synthesis of Nitrile-Functionalized Polydentate N-Heterocycles as Building Blocks for Covalent Triazine Frameworks-Reference-Cited by-同舟云学术

Synthesis of Nitrile-Functionalized Polydentate N-Heterocycles as Building Blocks for Covalent Triazine Frameworks

Published:2021-08-31 Issue: Volume: Page:
ISSN:0039-7881
Container-title:Synthesis
language:en
Short-container-title:Synthesis

Author:

Stevens Christian V.¹^ORCID,Everaert Jonas¹,Debruyne Maarten¹,Vanden Bussche Flore¹²,Van Hecke Kristof²,Heugebaert Thomas S. A.¹,Van Der Voort Pascal²,Van Speybroeck Veronique³

Affiliation:

1. SynBioC Research Group, Department of Green Chemistry and Technology, Faculty of Bioscience Engineering, Ghent University

2. Department of Chemistry, Faculty of Sciences, Ghent University

3. Center for Molecular Modeling (CMM), Ghent University

Abstract

AbstractCovalent triazine frameworks (CTFs) based on polydentate ligands are highly promising supports to anchor catalytic metal complexes. The modular nature of CTFs allows to tailor the composition, structure, and function to its specific application. Access to a broad range of chelating building blocks is therefore essential. In this respect, we extended the current available set of CTF building blocks with new nitrile-functionalized N-heterocyclic ligands. This paper presents the synthesis of the six ligands which vary in the extent of the aromatic system and the denticity. The new building blocks may help in a rational design of enhanced support materials in catalysis.

Funder

Bijzonder Onderzoeksfonds UGent

Fonds Wetenschappelijk Onderzoek

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry,Catalysis

Link

http://www.thieme-connect.de/products/ejournals/pdf/10.1055/a-1626-5749.pdf

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