A recyclable rhodium catalyst anchored onto a bipyridine covalent triazine framework for transfer hydrogenation of N-heteroarenes in water

Author:

Everaert Jonas1ORCID,Leus Karen2ORCID,Rijckaert Hannes3ORCID,Debruyne Maarten1,Van Hecke Kristof3ORCID,Morent Rino2,De Geyter Nathalie2ORCID,Van Speybroeck Veronique4ORCID,Van Der Voort Pascal3ORCID,Stevens Christian V.1ORCID

Affiliation:

1. SynBioC Research Group, Department of Green Chemistry and Technology, Faculty of Bioscience Engineering, Ghent University, Coupure Links 653, B-9000 Ghent, Belgium

2. Department of Applied Physics, Faculty of Engineering and Architecture, Ghent University, Sint-Pietersnieuwstraat 41-B4, B-9000 Ghent, Belgium

3. Department of Chemistry, Faculty of Sciences, Ghent University, Krijgslaan 281-S3, B-9000 Ghent, Belgium

4. Center for Molecular Modeling (CMM), Ghent University, Technologiepark 46, B-9052 Zwijnaarde, Belgium

Abstract

Bipyridine covalent triazine framework (bpyCTF) was used as a support material for the development of a highly efficient Rh catalyst. The heterogeneous catalyst was applied for both batch and flow transfer hydrogenation of various N-heteroarenes.

Funder

Fonds Wetenschappelijk Onderzoek

Universiteit Gent

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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