Organic Sulfinic Acids and Salts in Visible Light-Induced Reactions

Author:

Lu Hongjian1ORCID,Lu Zheng2ORCID,Shang Mingzhou1

Affiliation:

1. Institute of Chemistry and BioMedical Sciences, Jiangsu Key Laboratory of Advanced Organic Materials, School of Chemistry and Chemical Engineering, Nanjing University

2. School of Pharmacy, Jiangsu University

Abstract

AbstractSulfinic acids and their salts are a useful source of sulfur-containing structures. Photocatalysis of these compounds with visible light enables to achieve various transformations under mild conditions. This review summarizes visible-light-induced reactions of sulfinic acids and their salts. It is organized by reaction type and brief discussions on plausible reaction mechanisms for typical transformations are presented.1 Introduction2 Sulfonylation Reactions2.1 Sulfonylation of Alkenes2.2 Sulfonylation of Alkynes2.3 Sulfonylation of Arenes2.4 sp3 C–H Functionalization3 Desulfonylation Reactions4 Sulfenylation Reactions4.1 Sulfenylation of Heteroarenes4.2 Sulfenylation of Carbonyl Chlorides5 Conclusions

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry,Catalysis

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