Half-Sandwich d6-Metal (CoIII, RhIII, IrIII, RuII)-Catalyzed Enantioselective C

Half-Sandwich d6-Metal (CoIII, RhIII, IrIII, RuII)-Catalyzed Enantioselective C–H Activation

Published:2023-09-06 Issue:04 Volume:07 Page:466-485
ISSN:2509-9396
Container-title:SynOpen
language:en
Short-container-title:SynOpen

Author:

Qian Pu-Fan¹^ORCID,Li Jun-Yi¹,Zhou Yi-Bo¹,Zhou Tao¹,Shi Bing-Feng¹²³⁴^ORCID

Affiliation:

1. Center of Chemistry for Frontier Technologies, Department of Chemistry, Zhejiang University

2. College of Chemistry and Molecular Engineering, Zhengzhou University

3. School of Chemistry and Chemical Engineering, Henan Normal University

4. College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University

Abstract

AbstractTransition-metal-catalyzed enantioselective C–H activation provides a straightforward strategy to synthesize chiral molecules from readily available sources. In this graphical review, we summarize the progress on half-sandwich d6-metal (CoIII, RhIII, IrIII, RuII)-catalyzed enantioselective C–H functionalization reactions. The review is categorized according to the type of metal catalyst and chiral ligand employed. Representative enantio-determining models and catalytic cycles are presented.

Funder

National Natural Science Foundation of China

Zhejiang Provincial Natural Science Foundation

National Key Research and Development Program of China

Fundamental Research Funds for the Central Universities

Henan Normal University

Zhejiang University

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry,Materials Science (miscellaneous),Biomaterials,Catalysis

Link