Author:
Ishida Shintaro,Iwamoto Takeaki,Katayama Yasuhiro,Hirakawa Fumiya
Abstract
AbstractA stable dialkylphosphinyl radical reacted with bromoboranes to afford the corresponding phosphinoboranes accompanied with a bromophosphine under neutral condition at room temperature. The obtained phosphinoboranes have almost planar structures and have an effective P–B dative π-bond. The formation of phosphinoboranes would proceed via coordination-induced bromine abstraction from bromoboranes as a pivotal step, which was supported by the computational study.
Funder
Japan Society for the Promotion of Science
Cited by
1 articles.
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