Metal-catalyzed valence isomerization of a methylene(thioxo)phosphorane to a thiaphosphirane-Reference-Cited by-同舟云学术

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Metal-catalyzed valence isomerization of a methylene(thioxo)phosphorane to a thiaphosphirane

Published:2024 Issue:63 Volume:60 Page:8288-8291
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Ishida Shintaro¹^ORCID,Yoshida Yusuke¹^ORCID,Iwamoto Takeaki¹^ORCID

Affiliation:

1. Department of Chemistry, Graduate School of Science, Tohoku University, Aoba-ku, Sendai 980-8578, Japan

Abstract

A methylene(thioxo)phosphorane undergoes valence isomerization catalyzed by copper(i) chloride to furnish the corresponding thiaphosphirane. A mechanism involving a Cu-assisted cyclization reactions was supported theoretically.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC02147A

Reference52 articles.

1. Frontier orbital crossing and ambident reactivity in phosphorus(III) systems with (p–p)π-bonds

2. Recent developments in the chemistry of metallophosphaalkenes

3. Phosphaalkene, phospholyl and phosphinine ligands: New tools in coordination chemistry and catalysis

4. Catalytic applications of transition-metal complexes bearing diphosphinidenecyclobutenes (DPCB)

5. Organophosphorus π-Conjugated Materials

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