Affiliation:
1. Department of Chemistry, Federal University of São Carlos (UFSCar)
2. Department of Chemistry, State University of Santa Catarina (UDESC)
3. Department of Chemistry, Federal University of Santa Catarina (UFSC)
Abstract
AbstractAn electrochemical synthesis of flavanones via oxa-Michael addition using silver electrode as a sacrifice is reported. This electrosynthetic system showed good yields, broad substrate scope, and good functional group tolerance. Additionally, the method proved to be applicable on a gram-scale. Several studies were carried out to elucidate the reaction mechanism, such as control reactions, cyclic voltammetry, and theoretical studies, allowing the proposal of a plausible pathway for this transformation.
Funder
Fundação de Amparo à Pesquisa do Estado de São Paulo
Fundação de Amparo à Pesquisa e Inovação do Estado de Santa Catarina
Coordenação de Aperfeiçoamento de Pessoal de Nível Superior
INCT-Catálise
FAPESC
Subject
Organic Chemistry,Catalysis
Cited by
3 articles.
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