Modulating the reactivity of phosphanylidenephosphoranes towards water with Lewis acids-Reference-Cited by-同舟云学术

Modulating the reactivity of phosphanylidenephosphoranes towards water with Lewis acids

Published:2022 Issue:30 Volume:51 Page:11267-11276
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Dankert Fabian¹^ORCID,Fischer Malte¹²^ORCID,Hering-Junghans Christian¹^ORCID

Affiliation:

1. Leibniz Institut für Katalyse e.V., Katalyse mit phosphorhaltigen Materialien, Albert-Einstein-Straße 29a, 18059 Rostock, Germany

2. Inorganic Chemistry Laboratory, Department of Chemistry, University of Oxford, South Parks Road, Oxford, OX1 3QR, UK

Abstract

Prone to manipulations: Phospha-Wittig reagents react with water to give primary phosphine oxides, which form O-coordinated Lewis acid-base adducts. Adding the Lewis acid first and water in a second step afforded protio-phosphino-phosphonium cations.

Funder

Boehringer Ingelheim Stiftung

Leibniz-Gemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT01575G

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1. Über Triphenyl‐phosphinmethylene als olefinbildende Reagenzien (II. Mitteil. 1) )

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