Reactive FLP–alkyne addition products: a route to anionic and zwitterionic phosphines-Reference-Cited by-同舟云学术

Reactive FLP–alkyne addition products: a route to anionic and zwitterionic phosphines

Published:2023 Issue:16 Volume:52 Page:5023-5027
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kim Hyehwang¹^ORCID,Stephan Douglas W.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario M5S 3H6, Canada

Abstract

Anionic phosphine salts as well as a phosphine donor with both olefin-linked cationic and anionic substituents are derived from FLP–alkyne reactions using a phosphinidene precursor.

Funder

Natural Sciences and Engineering Research Council of Canada

Canada Council for the Arts

Royal Society of Chemistry

American Chemical Society

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT00607G

Reference39 articles.

1. Deprotonation and Addition Reactions of Frustrated Lewis Pairs with Alkynes

2. Terminal Alkyne Activation by Frustrated and Classical Lewis Acid/Phosphine Pairs

3. Chloro- and phenoxy-phosphines in frustrated Lewis pair additions to alkynes

4. New Strategies to Phosphino-Phosphonium Cations and Zwitterions

5. Addition of Enamines or Pyrroles and B(C6F5)3 “Frustrated Lewis Pairs” to Alkynes

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