Surface-assisted cis–trans isomerization of an alkene molecule on Cu(110)-Reference-Cited by-同舟云学术

Surface-assisted cis–trans isomerization of an alkene molecule on Cu(110)

Published:2014 Issue:14 Volume:50 Page:1728-1730
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Sun Qiang¹²³⁴,Zhang Chi¹²³⁴,Wang Likun¹²³⁴,Li Zhiwen⁵⁶⁷⁸,Hu Aiguo⁵⁶⁷⁸,Tan Qinggang¹²³⁴,Xu Wei¹²³⁴

Affiliation:

1. College of Materials Science and Engineering

2. Key Laboratory for Advanced Civil Engineering Materials (Ministry of Education)

3. Tongji University

4. Shanghai 201804, P. R. China

5. School of Materials Science and Engineering

6. Shanghai Key Laboratory of Advanced Polymeric Materials

7. East China University of Science and Technology

8. Shanghai 200237, P. R. China

Abstract

Interplay of STM imaging and DFT calculations demonstrates the isomerization of an alkene molecule on Cu(110) under ultrahigh vacuum conditions. We show that the on-surfacecis–transisomerization could efficiently occur well below room temperature, in which the surface is speculated to play a key role in assisting this isomerization process.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C3CC48992B

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