Hydrogenase biomimics containing redox-active ligands: Fe2(CO)4(μ-edt)(κ2-bpcd) with electron-acceptor 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd) as a potential [Fe4

Hydrogenase biomimics containing redox-active ligands: Fe2(CO)4(μ-edt)(κ2-bpcd) with electron-acceptor 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd) as a potential [Fe4–S4]H surrogate

Published:2019 Issue:18 Volume:48 Page:6051-6060
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Ghosh Shishir¹²³⁴¹^ORCID,Hollingsworth Nathan¹⁵⁶⁴,Warren Mark⁷⁸⁴,Hrovat David A.⁹¹⁰¹¹¹²¹,Richmond Michael G.¹¹⁰¹¹¹²^ORCID,Hogarth Graeme¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. King's College London

3. London SE1 1DB

4. UK

5. University College London

6. London WC1H OAJ

7. Diamond Light Source

8. Didcot

9. Center for Advanced Scientific Computing and Modeling

10. University of North Texas

11. Denton

12. USA

Abstract

The diiron centre and redox-active diphosphine are reduced in separate steps but there is little evidence of intramolecular electron transfer between the two.

Funder

Commonwealth Scholarship Commission

Engineering and Physical Sciences Research Council

King’s College London

Welch Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT04906H

Reference56 articles.