Highly branched unsaturated polyethylenes achievable using strained imino-cyclopenta[b]pyridyl-nickel precatalysts-Reference-Cited by-同舟云学术

Highly branched unsaturated polyethylenes achievable using strained imino-cyclopenta[b]pyridyl-nickel precatalysts

Published:2017 Issue:6 Volume:8 Page:995-1005
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Zhang Youfu¹²³⁴⁵,Huang Chuanbing⁵⁶⁷⁸⁴,Wang Xinxin⁵⁶⁷⁸⁴,Mahmood Qaiser⁵⁶⁷⁸⁴,Hao Xiang⁵⁶⁷⁸⁴,Hu Xinquan¹²³⁴,Guo Cun-Yue⁹¹⁰¹¹⁴,Solan Gregory A.⁵⁶⁷⁸⁴^ORCID,Sun Wen-Hua⁵⁶⁷⁸⁴^ORCID

Affiliation:

1. College of Chemical Engineering

2. Zhejiang University of Technology

3. Hangzhou 310014

4. China

5. Key Laboratory of Engineering Plastics and Beijing National Laboratory for Molecular Science

6. Institute of Chemistry

7. Chinese Academy of Sciences

8. Beijing 100190

9. School of Chemistry and Chemical Engineering

10. University of Chinese Academy of Sciences

11. Beijing 100049

Abstract

Highly branched and unsaturated PEs with narrow PDIs have been obtained using nickel catalysts that display high activities, rapid regeneration of active species and high rates of chain isomerization.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2017/PY/C6PY02089E

Reference70 articles.

1. New Pd(II)- and Ni(II)-Based Catalysts for Polymerization of Ethylene and .alpha.-Olefins

2. Novel Polyethylenes via Late Transition Metal Complex Pre-catalysts

3. Nickel complex pre-catalysts in ethylene polymerization: new approaches to elastomeric materials