Gd(iii) and Mn(ii) complexes for dynamic nuclear polarization: small molecular chelate polarizing agents and applications with site-directed spin labeling of proteins-Reference-Cited by-同舟云学术

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Gd(iii) and Mn(ii) complexes for dynamic nuclear polarization: small molecular chelate polarizing agents and applications with site-directed spin labeling of proteins

Published:2016 Issue:39 Volume:18 Page:27205-27218
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Kaushik Monu¹²³⁴⁵,Bahrenberg Thorsten¹²³⁴⁵,Can Thach V.⁶⁷⁸⁹,Caporini Marc A.¹⁰¹¹⁹,Silvers Robert⁵²³⁴⁶,Heiliger Jörg¹²³⁴⁵,Smith Albert A.⁶⁷⁸⁹,Schwalbe Harald⁵²³⁴¹²,Griffin Robert G.⁶⁷⁸⁹,Corzilius Björn¹²³⁴⁵

Affiliation:

1. Institute of Physical and Theoretical Chemistry and Institute of Biophysical Chemistry

2. Goethe University Frankfurt

3. 60438 Frankfurt am Main

4. Germany

5. Center for Biomolecular Magnetic Resonance (BMRZ)

6. Francis Bitter Magnet Laboratory and Department of Chemistry

7. Massachusetts Institute of Technology

8. Cambridge

9. USA

10. Bruker Biospin Ltd.

11. Billerica

12. Institute of Organic Chemistry and Chemical Biology

Abstract

Metal complexes based on Gd(iii) and Mn(ii) spin-labels can be utilized for dynamic nuclear polarization of ¹H, ¹³C, and ¹⁵N.

Funder

Deutsche Forschungsgemeinschaft

National Institute of Biomedical Imaging and Bioengineering

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP04623A

Reference97 articles.

1. Polarization-Enhanced NMR Spectroscopy of Biomolecules in Frozen Solution

2. Dynamic nuclear polarization with a cyclotron resonance maser at 5 T

3. High frequency (140 GHz) dynamic nuclear polarization: Polarization transfer to a solute in frozen aqueous solution

4. 250GHz CW gyrotron oscillator for dynamic nuclear polarization in biological solid state NMR

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