Synthesis and magnetochemistry of heterometallic triangular FeIII2LnIII (Ln = La, Gd, Tb, Dy, and Ho) and FeIII2YIII complexes-Reference-Cited by-同舟云学术

Synthesis and magnetochemistry of heterometallic triangular FeIII2LnIII (Ln = La, Gd, Tb, Dy, and Ho) and FeIII2YIII complexes

Published:2017 Issue:24 Volume:46 Page:7897-7903
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Singh Namrata¹²³⁴^ORCID,Das Gupta Sayak¹⁵⁶⁷,Butcher Raymond J.¹⁸⁹⁷,Christou George¹⁵⁶⁷

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Kanpur

3. Kanpur-208016

4. India

5. University of Florida

6. Gainesville

7. USA

8. Howard University

9. Washington

Abstract

A series of six 3d–4f mixed metal complexes with an Fe₂M(μ₃-O) triangular core have been synthesized and characterized by X-ray crystallography. Magnetic studies of the compounds reveal a spin frustrated system due to the strong Fe⋯Fe antiferromagnetic interaction.

Funder

Department of Science and Technology, Ministry of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT00949F

Reference69 articles.

1. Filling the gap between the quantum and classical worlds of nanoscale magnetism: giant molecular aggregates based on paramagnetic 3d metal ions

2. Magnetic anisotropy in two- to eight-coordinated transition–metal complexes: Recent developments in molecular magnetism

3. Magnetic materials based on 3d metal phosphonates