Photoelectrochemical CO2 reduction using a Ru(ii)–Re(i) multinuclear metal complex on a p-type semiconducting NiO electrode-Reference-Cited by-同舟云学术

Photoelectrochemical CO2 reduction using a Ru(ii)–Re(i) multinuclear metal complex on a p-type semiconducting NiO electrode

Published:2015 Issue:53 Volume:51 Page:10722-10725
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Sahara Go¹²³⁴⁵,Abe Ryu⁶⁷⁸⁹⁵,Higashi Masanobu⁶⁷⁸⁹⁵,Morikawa Takeshi¹⁰¹¹⁵,Maeda Kazuhiko¹²³⁴⁵,Ueda Yutaro¹²³⁴⁵,Ishitani Osamu¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Graduate School of Science and Engineering

3. Tokyo Institute of Technology

4. Tokyo 152-8550

5. Japan

6. Department of Energy and Hydrocarbon Chemistry

7. Graduate School of Engineering

8. Kyoto University

9. Kyoto 615-8510

10. Toyota Central Research and Development Laboratories, Inc.

11. Nagakute

Abstract

A photocathode for CO₂ reduction was developed using a hybrid comprising a Ru(ii)–Re(i) supramolecular photocatalyst and a NiO electrode. Photoexcitation of the Ru photosensitizer selectively gave CO with high faradaic efficiency.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CC/C5CC02403J

Reference13 articles.

1. Substantial improvement in the efficiency and durability of a photocatalyst for carbon dioxide reduction using a benzoimidazole derivative as an electron donor

2. Solar CO2 reduction using H2O by a semiconductor/metal-complex hybrid photocatalyst: enhanced efficiency and demonstration of a wireless system using SrTiO3 photoanodes

3. Visible light-induced reduction of carbon dioxide sensitized by a porphyrin–rhenium dyad metal complex on p-type semiconducting NiO as the reduction terminal end of an artificial photosynthetic system

4. A Visible-Light Harvesting System for CO2Reduction Using a RuII-ReIPhotocatalyst Adsorbed in Mesoporous Organosilica

5. Artificial Z-Scheme Constructed with a Supramolecular Metal Complex and Semiconductor for the Photocatalytic Reduction of CO2

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