Metal- and ligand-substitution-induced changes in the kinetics and thermodynamics of hydrogen activation and hydricity in a dinuclear metal complex-Reference-Cited by-同舟云学术

Metal- and ligand-substitution-induced changes in the kinetics and thermodynamics of hydrogen activation and hydricity in a dinuclear metal complex

Published:2024 Issue:13 Volume:53 Page:5966-5978
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Isegawa Miho¹^ORCID

Affiliation:

1. International Institute for Carbon-Neutral Energy Research (WPI-I2CNER), Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka, 819-0395, Japan

Abstract

The density functional theory calculations revealed that the following order thermodynamically favored hydrogen activation: [NiFe(CO)]2+ > [NiRu(CO)]2+ > [NiFe(CNMe)]2+ ∼ [PdRu(CO)]2+ ∼ [PdFe(CO)]2+ ≫ [NiFe(NCS)]+.

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00361F

Reference60 articles.

1. Power of the Secondary Sphere: Modulating Hydrogenase Activity in Nickel-Substituted Rubredoxin

2. Second and Outer Coordination Sphere Effects in Nitrogenase, Hydrogenase, Formate Dehydrogenase, and CO Dehydrogenase

3. Recent developments in bioinspired modelling of [NiFe]- and [FeFe]-hydrogenases

4. A review of non-precious metal single atom confined nanomaterials in different structural dimensions (1D–3D) as highly active oxygen redox reaction electrocatalysts

5. Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Recent advancement in viologen functionalized porous organic polymers (vPOPs) for energy and environmental remediation;Materials Advances;2024