The development of a robust folded scaffold as a fluorescent material using butylidine-linked pyridazinone-based systems via aromatic π⋯π stacking interactions

Author:

Yadav Priyanka1,Verma Abhineet1ORCID,Sharma Vishal Prasad1,Singh Rashmi1,Yadav Tarun2,Kumar Ranjeet3,Pal Shiv4,Gupta Hariom5ORCID,Saha Satyen1ORCID,Tewari Ashish K.1ORCID

Affiliation:

1. Department of Chemistry, Institute of Science, Banaras Hindu University, Varanasi, Uttar Pradesh-221005, India

2. Department of Physics, Institute of Science, Banaras Hindu University, Varanasi, Uttar, Pradesh-221005, India

3. Department of Chemistry, CMP Degree College, Prayagraj, Uttar Pradesh-211002, India

4. Department of Chemistry, Indian Institute of Technology, Bombay-400076, India

5. Phytochemistry Division, CSIR-Central Institute of Medicinal and Aromatics Plants (CSIR-CIMAP), Lucknow-226015, India

Abstract

Fluorescence-capable robust folded pyridazinone-based homo- and heterodimers linked with butylidine linkers, whose crystals exhibit fluorescence with quantum yields of 11% (1CN) and 28% (2CN) due to intramolecular stacking, were synthesized.

Funder

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference39 articles.

1. π-Stacking Interactions

2. Aromatic−Aromatic Interactions in Crystal Structures of Helical Peptide Scaffolds Containing Projecting Phenylalanine Residues

3. S. K.Rai , P.Singh , R.Kumar , A. K.Tewari , J.Hostaš , R.Gnanasekaran and P.Hobza , Experimental and Theoretical Study for the Assessment of the Conformational Stability of Polymethylene-Bridged Heteroaromatic Dimers: A Case of Unprecedented Folding , Cryst. Growth Des. , 2016 , 16, 1176–1180

4. A Case of Folding Pattern in Flexible Tripodal of N-Substituted Bisethylenamine Bridged Pyridazinone Dimers

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