Utilizing Baylis–Hillman Adducts Followed by Michael Addition/Elimination Reaction for the Synthesis of Unusual Conformationally Stable Molecules Governed by Aromatic Interactions-Reference-Cited by-同舟云学术

Utilizing Baylis–Hillman Adducts Followed by Michael Addition/Elimination Reaction for the Synthesis of Unusual Conformationally Stable Molecules Governed by Aromatic Interactions

Published:2023-12-04 Issue:48 Volume:26 Page:
ISSN:1434-193X
Container-title:European Journal of Organic Chemistry
language:en
Short-container-title:Eur J Org Chem

Author:

Prasad Sharma Vishal¹,Kumar Vipin¹,Sonker Priyanka¹,Yadav Priyanka¹,Singh Rashmi¹,Gnanasekaran Ramachandran²,Kumar Tewari Ashish¹^ORCID

Affiliation:

1. Department of Chemistry (Centre of Advanced Study) Institute of Science Banaras Hindu University Varanasi 221005 India

2. VIT-University Chennai-600127 Tamil Nadu India

Abstract

AbstractThe compounds under investigation sought a new approach to synthesis via the Baylis‐Hillman (B−H) and Michael addition reactions. The product formation‘s legitimacy was tested using a repeat reaction with many different nucleophiles. The additional stability of the product via aromatic π⋅⋅⋅π and C−H⋅⋅⋅π interactions may result in unexpected product formation in diverse reactions undertaken utilizing different starting materials. This study suggests that weak interaction not only provides selectivity during reactions but also modifies the result.

Publisher

Wiley

Subject

Organic Chemistry,Physical and Theoretical Chemistry

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