Packing polymorphism in 3-amino-2-pyrazinecarboxylate based tin(ii) complexes and their catalytic activity towards cyanosilylation of aldehydes

Author:

Karmakar Anirban12345ORCID,Hazra Susanta12345ORCID,Rúbio Guilherme M. D. M.12345,Guedes da Silva M. Fátima C.12345ORCID,Pombeiro Armando J. L.12345ORCID

Affiliation:

1. Centro de Química Estrutural

2. Instituto Superior Técnico

3. Universidade de Lisboa

4. Av. Rovisco Pais

5. Lisbon

Abstract

3-Amino-2-pyrazinecarboxylic acid is used to synthesize two new mononuclear interconvertible packing polymorphs of tin(ii) which act as heterogeneous catalysts for the cyanosilylation of aldehydes with trimethylsilyl cyanide.

Funder

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference117 articles.

1. J. Bernstein , Polymorphism in Molecular Crystals , Oxford University Press , 2002

2. J. A. R. P. Sarma and G. R.Desiraju , Crystal Engineering: The Design and Application of Functional Solids , ed. K. R. Seddon , M. J. Zaworotko , Kluwer , Dordrecht , 1999 , vol. 539, pp. 325–356

3. Polymorphism in cocrystals: a review and assessment of its significance

4. Polymorphism − A Perspective

5. Polymorphism, what it is and how to identify it: a systematic review

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