Inference of principal species in caustic aluminate solutions through solid-state spectroscopic characterization
Author:
Affiliation:
1. Pacific Northwest National Laboratory
2. Richland
3. USA
4. Department of Chemistry
5. Washington State University
6. Pullman
7. Advanced Light Source
8. Lawrence Berkeley National Laboratory
9. Berkeley
Abstract
Tetrahedrally coordinated Al(OH)4− and Al2O(OH)62− have been isolated in the solid-state and interrogated using XRD, NMR, XAS, IR, and Raman.
Funder
Basic Energy Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT00229A
Reference70 articles.
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5. 27Al Pulsed Field Gradient, Diffusion–NMR Spectroscopy of Solvation Dynamics and Ion Pairing in Alkaline Aluminate Solutions
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