An amorphous sodium aluminate hydrate phase mediates aluminum coordination changes in highly alkaline sodium hydroxide solutions-Reference-Cited by-同舟云学术

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An amorphous sodium aluminate hydrate phase mediates aluminum coordination changes in highly alkaline sodium hydroxide solutions

Published:2022 Issue:24 Volume:9 Page:6344-6357
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Graham Trent R.¹^ORCID,Hu Jian Zhi¹²,Jaegers Nicholas R.¹^ORCID,Zhang Xin¹^ORCID,Pearce Carolyn I.¹³^ORCID,Rosso Kevin M.¹^ORCID

Affiliation:

1. Pacific Northwest National Laboratory, Richland, WA 99354, USA

2. The Gene and Linda Voiland School of Chemical Engineering and Bioengineering, Washington State University, Pullman, WA 99164, USA

3. Department of Crop & Soil Sciences, Washington State University, Pullman, WA 99164, USA

Abstract

A newly identified intermediate phase containing tetrahedral Al is formed incipient to the crystallization of sodium aluminate hydrates.

Funder

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QI/D2QI01642G

Reference41 articles.

1. Raman, IR, and 27Al-MAS-NMR Spectroscopic Studies of Sodium (Hydroxy)Aluminates

2. The structure of Al(III) in strongly alkaline aluminate solutions — A review

3. Basic concepts of the crystallization from aqueous solutions: The example of aluminum oxy(hydroxi)des and aluminosilicates

4. Nonanatrium-bis(hexahydroxoaluminat)-trihydroxid-hexahydrat (Na9[Al(OH)6]2(OH)3 � 6H2O) - Kristallstruktur, NMR-Spektroskopie und thermisches Verhalten

5. Nonasodium Bis(hexahydroxoaluminate) Trihydroxide Hexahydrate

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