<i>Z</i>-selective radical difunctionalization of aromatic alkynes: synthesis of multi-substituted triarylethenes-Reference-Cited by-同舟云学术

Z-selective radical difunctionalization of aromatic alkynes: synthesis of multi-substituted triarylethenes

Published:2024 Issue:37 Volume:60 Page:4894-4897
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Wang Xinxin¹,Wang Jie¹,Ji Meishan¹,Wu Xinxin¹^ORCID,Zhu Chen¹²^ORCID

Affiliation:

1. Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 199 Ren-Ai Road, Suzhou, Jiangsu 215123, China

2. Frontiers Science Center for Transformative Molecules and Shanghai Key Laboratory for Molecular Engineering of Chiral Drugs, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, China

Abstract

Described herein is a Cu-catalyzed diarylation of aromatic alkynes via radical docking-migration pathways, leading to a broad range of valuable triarylethenes.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Program of Shanghai Academic Research Leader

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC01315H

Reference36 articles.

1. Substituted-vinyl hydroxytriarylethylenes, 1-[4-[2-(diethylamino)ethoxy]phenyl]-1-(4-hydroxyphenyl)-2-phenylethylenes: synthesis and effects on MCF 7 breast cancer cell proliferation

2. Identification of GDC-0810 (ARN-810), an Orally Bioavailable Selective Estrogen Receptor Degrader (SERD) that Demonstrates Robust Activity in Tamoxifen-Resistant Breast Cancer Xenografts

3. Stereoselective synthesis of triarylethylenes via copper–palladium catalyzed decarboxylative cross-coupling: synthesis of (Z)-tamoxifen

4. Triphenylethylene carbazole derivatives as a new class of AIE materials with strong blue light emission and high glass transition temperature

5. Combined aggregation induced emission (AIE), photochromism and photoresponsive wettability in simple dichloro-substituted triphenylethylene derivatives

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