Bio-inspired design of an in situ multifunctional polymeric solid–electrolyte interphase for Zn metal anode cycling at 30 mA cm−2 and 30 mA h cm−2-Reference-Cited by-同舟云学术

Bio-inspired design of an in situ multifunctional polymeric solid–electrolyte interphase for Zn metal anode cycling at 30 mA cm−2 and 30 mA h cm−2

Published:2021 Issue:11 Volume:14 Page:5947-5957
ISSN:1754-5692
Container-title:Energy & Environmental Science
language:en
Short-container-title:Energy Environ. Sci.

Author:

Zeng Xiaohui¹,Xie Kaixuan²,Liu Sailin¹,Zhang Shilin¹³^ORCID,Hao Junnan³^ORCID,Liu Jiatu⁴,Pang Wei Kong¹^ORCID,Liu Jianwen⁵^ORCID,Rao Pinhua⁶^ORCID,Wang Qinghong²^ORCID,Mao Jianfeng¹³^ORCID,Guo Zaiping¹³^ORCID

Affiliation:

1. Institute for Superconducting and Electronic Materials (ISEM), Australian Institute for Innovative Materials (AIIM), University of Wollongong, NSW 2522, Australia

2. School of Chemistry and Materials Science, Jiangsu Normal University, Xuzhou, Jiangsu, 221116, P. R. China

3. School of Chemical Engineering & Advanced Materials, University of Adelaide, Adelaide, SA 5005, Australia

4. School of Mechanical and Manufacturing Engineering, University of New South Wales, Sydney, NSW 2052, Australia

5. College of Chemistry and Chemical Engineering, Hubei University, Wuhan 430062, P. R. China

6. College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai 201620, P. R. China

Abstract

We report a bio-inspired design strategy for constructing an in situ polymeric SEI in aqueous Zn chemistry. This SEI can restrain interfacial side reactions, facilitate a uniform Zn2+ flux, and consequently endow a highly stable Zn metal anode.

Funder

Australian Research Council

China Scholarship Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/EE/D1EE01851E

Reference45 articles.

1. Monolithic solid–electrolyte interphases formed in fluorinated orthoformate-based electrolytes minimize Li depletion and pulverization

2. Voltage issue of aqueous rechargeable metal-ion batteries