High‐Capacity Zinc Anode Enabled by a Recyclable Biomass Bamboo Membrane Separator

Author:

Ma Jianfeng1,Shi Xin2,Wang Zhihui1,Zhou Lijun2,Liu Xinge1,Lu Xihong2ORCID,Jiang Zehui1

Affiliation:

1. Key Lab of Bamboo and Rattan Science & Technology International Center for Bamboo and Rattan Beijing 100102 P. R. China

2. MOE of the Key Laboratory of Bioinorganic and Synthetic Chemistry The Key Lab of Low‐carbon Chem & Energy Conservation of Guangdong Province School of Chemistry Sun Yat‐Sen University Guangzhou 510275 P. R. China

Abstract

AbstractAqueous zinc ion batteries have gained attention as viable energy storage systems, yet the occurrence of detrimental side reactions and Zn dendrite formation undermines the efficiency of Zn anodes. Controlling water activity have proven to be an effective strategy in mitigating these challenges. However, strategies such as electrolyte design and electrode protection layer show weakness to varying degrees. Here, a new oxygen‐functionalized biomass bamboo membrane separator (denoted as BM) is proposed to restrain the activity of water molecules. This BM separator features a unique, multi‐tiered 2D interlayer that facilitates rapid ion diffusion. Additionally, the oxygen functional groups of the BM separator can form hydrogen bonds with water molecules, effectively transforming water molecules from a free state to a bound state. Consequently, the Zn/Zn asymmetric coin cell using BM can work at the ultrahigh rate and capacity of 30 mA cm−2 and 30 mAh cm−2 for more than 80 h while its counterparts using glass fiber can barely work. Moreover, full cells using BM separator exhibited a capacity retention of 89.7% after 1000 cycles at 10 A g−1. This study reveals the important influence of water‐limited activity on Zn anode protection and provides an avenue for the design of novel separator.

Funder

National Key Research and Development Program of China

Publisher

Wiley

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3