Nanoscale electrochemistry in a copper/aqueous/oil three-phase system: surface structure–activity-corrosion potential relationships

Author:

Daviddi Enrico1234ORCID,Shkirskiy Viacheslav1234,Kirkman Paul M.564,Robin Mathew P.564ORCID,Bentley Cameron L.12347ORCID,Unwin Patrick R.1234ORCID

Affiliation:

1. Department of Chemistry

2. University of Warwick

3. Coventry CV4 7AL

4. UK

5. Lubrizol LTD

6. Hazelwood DE56 4AN

7. School of Chemistry

Abstract

Probing Cu corrosion in an aqueous nanodroplet/oil/metal three-phase environment revealed unique patterns of surface reactivity. The electrochemistry of high-index facets cannot be predicted simply from the low-index {001}, {011} and {111} responses.

Funder

Ramsay Memorial Fellowships Trust, University College London

H2020 Marie Skłodowska-Curie Actions

Australian Research Council

University of Warwick

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference87 articles.

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2. G. H. Koch , M. P. H.Brongers , N. G.Thompson , Y. P.Virmani and J. H.Payer , Corrosion Cost and Preventive Strategies in the United States, Report by CC Technologies Laboratories, Inc. to Federal Highway Administration (FHWA) , Office of Infrastructure Research and Development , McLean , 2001

3. P. Marcus and F. B.Mansfeld , Analytical Methods In Corrosion Science and Engineering , CRC Press , 2005

4. Recent Developments in Electrochemistry–Mass Spectrometry

5. Anodic Dissolution of 304 Stainless Steel Using Atomic Emission Spectroelectrochemistry

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