Access to distal biaxial atropisomers by iridium catalyzed asymmetric C–H alkylation-Reference-Cited by-同舟云学术

Access to distal biaxial atropisomers by iridium catalyzed asymmetric C–H alkylation

Published:2024 Issue:33 Volume:15 Page:13541-13549
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Hu Xueqing¹,Zhao Yunxu¹,He Tong²,Niu Caoyue¹,Liu Feipeng¹,Jia Wei¹,Mu Yi¹,Li Xingwei²^ORCID,Rong Zi-Qiang¹^ORCID

Affiliation:

1. Frontiers Science Center for Flexible Electronics (FSCFE), Shaanxi Institute of Flexible Electronics (SIFE), Northwestern Polytechnical University (NPU), Xi'an 710072, China

2. School of Chemistry and Chemical Engineering, Shaanxi Normal University (SNNU), Xi'an 710119, China

Abstract

Herein, we report an iridium-catalyzed asymmetric C–H activation combined with a desymmetrization strategy for synthesizing distal biaxial atropisomers with excellent stereoselectivity, displaying promising photophysical and chiroptical properties.

Funder

National Natural Science Foundation of China

Natural Science Basic Research Program of Shaanxi Province

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC01837K

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