Direct structural and mechanistic insights into fast bimolecular chemical reactions in solution through a coupled XAS/UV–Vis multivariate statistical analysis

Author:

Tavani Francesco1234,Capocasa Giorgio1234,Martini Andrea15647,Sessa Francesco1234ORCID,Di Stefano Stefano1234ORCID,Lanzalunga Osvaldo1234ORCID,D'Angelo Paola1234ORCID

Affiliation:

1. Dipartimento di Chimica

2. Università di Roma “La Sapienza”

3. 00185 Roma

4. Italy

5. Università degli Studi di Torino

6. 10125 Torino

7. The Smart Materials Research Institute

Abstract

A combined multivariate and theoretical analysis of coupled XAS/UV–Vis data was proven to be an innovative method to obtain direct structural and mechanistic evidence for bimolecular reactions in solution involving organic substrates.

Funder

Ministero dell’Istruzione, dell’Università e della Ricerca

Sapienza Università di Roma

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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