Rational design of dinitroxide biradicals for efficient cross-effect dynamic nuclear polarization-Reference-Cited by-同舟云学术

Rational design of dinitroxide biradicals for efficient cross-effect dynamic nuclear polarization

Published:2016 Issue:1 Volume:7 Page:550-558
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kubicki Dominik J.¹²³⁴,Casano Gilles⁵⁶⁷⁸⁹,Schwarzwälder Martin¹⁰¹¹¹²⁴,Abel Sébastien⁵⁶⁷⁸⁹,Sauvée Claire⁵⁶⁷⁸⁹,Ganesan Karthikeyan⁵⁶⁷⁸⁹,Yulikov Maxim¹⁰¹¹¹²⁴,Rossini Aaron J.¹²³⁴,Jeschke Gunnar¹⁰¹¹¹²⁴,Copéret Christophe¹⁰¹¹¹²⁴,Lesage Anne¹³¹⁴¹⁵¹⁶⁹,Tordo Paul⁵⁶⁷⁸⁹,Ouari Olivier⁵⁶⁷⁸⁹,Emsley Lyndon¹²³⁴

Affiliation:

1. Institut des Sciences et Ingénierie Chimiques

2. Ecole Polytechnique Fédérale de Lausanne (EPFL)

3. CH-1015 Lausanne

4. Switzerland

5. Aix-Marseille Université

6. CNRS

7. ICR UMR 7273

8. 13397 Marseille

9. France

10. ETH Zurich

11. Department of Chemistry, Laboratory of Inorganic Chemistry

12. 8093 Zurich

13. Université de Lyon

14. Institut de Sciences Analytiques (CNRS / ENS de Lyon / UCB-Lyon 1)

15. Centre de RMN à Très Hauts Champs

16. 69100 Villeurbanne

Abstract

A series of 37 dinitroxide biradicals have been prepared and their performance studied as polarizing agents in cross-effect DNP NMR experiments at 9.4 T and 100 K in 1,1,2,2-tetrachloroethane (TCE).

Funder

European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC02921J

Reference72 articles.

1. Polarization of Nuclear Spins in Metals

2. M. Goldman , Spin Temperature and Nuclear Magnetic Resonance in Solids (Monographs on Physics), Oxford University Press, 1970

3. A. Abragam and M.Goldman, Nuclear Magnetism: Order and Disorder (Monographs on Physics), Oxford University Press, 1982