Phosphite mediated asymmetric N to C migration for the synthesis of chiral heterocycles from primary amines-Reference-Cited by-同舟云学术

Phosphite mediated asymmetric N to C migration for the synthesis of chiral heterocycles from primary amines

Published:2021 Issue: Volume: Page:
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Rani Soniya¹²³⁴⁵,Dash Soumya Ranjan⁵⁶⁴⁷²^ORCID,Bera Asish¹²³⁴⁵,Alam Md Nirshad¹²³⁴⁵,Vanka Kumar⁵⁶⁴⁷²^ORCID,Maity Pradip¹²³⁴^ORCID

Affiliation:

1. Organic Chemistry Division

2. CSIR-National Chemical Laboratory

3. Pune-411008

4. India

5. Academy of Scientific and Innovative Research (AcSIR)

6. Ghaziabad-201002

7. Physical and Material Chemistry Division

Abstract

N-Alkylpyridinium salt of chiral amines undergoes phosphite mediated stereoretentive migrations to generate chiral alkylpyridines. The role of phosphite on reactivity and stereoselectivity were examined to achieve a catalytic asymmetric version.

Funder

Science and Engineering Research Board

Council of Scientific and Industrial Research, India

University Grants Commission

Indian Institute of Science Education and Research Pune

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC01217G

Reference105 articles.

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4. Generation of Alkyl Radicals: From the Tyranny of Tin to the Photon Democracy

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