Synthesis and characterization of a modified “picket fence” porphyrin complex – stronger π bonding interactions between Fe(ii) and axial ligands
Author:
Affiliation:
1. College of Materials Science and Opto-electronic Technology
2. University of Chinese Academy of Sciences
3. Beijing
4. China
5. Department of Physics
6. Knox College
7. USA
Abstract
The synthesis and characterization of [Fe(MbenTpivPP)(1-MeIm)2], a new species among bis(imidazole) iron(ii) porphyrinates, is reported. Investigations suggest a strong correlation between mutual ligand orientations (θ) and axial Fe–NIm bond distances.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00941C
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