Structurally characterised intermediate of the oxidative addition of a heteroleptic germylene to gallanediyle-Reference-Cited by-同舟云学术

Structurally characterised intermediate of the oxidative addition of a heteroleptic germylene to gallanediyle

Published:2022 Issue:70 Volume:58 Page:9758-9761
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Bücker Anna¹,Wölper Christoph¹,Haberhauer Gebhard²^ORCID,Schulz Stephan¹³^ORCID

Affiliation:

1. Institute of Inorganic Chemistry, University of Duisburg-Essen, 45117 Essen, Germany

2. Institute of Organic Chemistry, University of Duisburg-Essen, 45117 Essen, Germany

3. Center for Nanointegration Duisburg-Essen (Cenide), University of Duisburg-Essen, 47057 Duisburg, Germany

Abstract

Reactions of gallanediyl LGa with heteroleptic tetrylenes L′ECl gave the donor–acceptor complex LGa–Sn(Cl)L′ (1), the oxidative addition product L(Cl)GaGeL′ (3) and LGa(μ–Cl)GeL′ (2), an isolable intermediate of the oxidative addition reaction.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC03561H

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