Defect-mediated selective hydrogenation of nitroarenes on nanostructured WS2

Author:

Sun Yifan12342ORCID,Darling Albert J.123,Li Yawei523ORCID,Fujisawa Kazunori62342,Holder Cameron F.123,Liu He123,Janik Michael J.523,Terrones Mauricio12362ORCID,Schaak Raymond E.12352ORCID

Affiliation:

1. Department of Chemistry and Materials Research Institute

2. The Pennsylvania State University

3. USA

4. Center for 2-Dimensional and Layered Materials

5. Department of Chemical Engineering

6. Department of Physics

Abstract

Colloidal 2H-WS2 nanostructures catalyze selective hydrogenation of substituted nitroarenes to anilines with molecular hydrogen, where sulfur vacancies and tungsten-terminated edges play key roles in enabling functional group selectivity.

Funder

Air Force Office of Scientific Research

American Chemical Society Petroleum Research Fund

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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