Nanostructured transition metal dichalcogenide electrocatalysts for CO 2 reduction in ionic liquid

Author:

Asadi Mohammad1,Kim Kibum12,Liu Cong3,Addepalli Aditya Venkata1,Abbasi Pedram1,Yasaei Poya1,Phillips Patrick4,Behranginia Amirhossein1,Cerrato José M.5,Haasch Richard6,Zapol Peter3,Kumar Bijandra17,Klie Robert F.4,Abiade Jeremiah1,Curtiss Larry A.3,Salehi-Khojin Amin1

Affiliation:

1. Department of Mechanical and Industrial Engineering, University of Illinois, Chicago, IL 60607, USA.

2. Department of Mechanical Engineering, Chungbuk National University, Cheongju 361-763, South Korea.

3. Materials Science Division, Argonne National Laboratory, Argonne, IL 60439, USA.

4. Department of Physics, University of Illinois at Chicago, Chicago, IL 60607, USA.

5. Department of Civil Engineering, University of New Mexico, Albuquerque, NM 87131, USA.

6. Materials Research Laboratory, University of Illinois at Urbana-Champaign, Urbana, IL 61801, USA.

7. Conn Center for Renewable Energy Research, University of Louisville, Louisville, KY 40292, USA.

Abstract

Small and salty CO 2 reduction scheme Most artificial photosynthesis approaches focus on making hydrogen. Modifying CO 2 , as plants and microbes do, is more chemically complex. Asadi et al. report that fashioning WSe 2 and related electrochemical catalysts into nanometer-scale flakes greatly improves their activity for the reduction of CO 2 to CO. An ionic liquid reaction medium further enhances efficiency. An artificial leaf with WSe 2 reduced CO 2 on one side while a cobalt catalyst oxidized water on the other side. Science , this issue p. 467

Funder

NSF

University of Chicago

MRSEC

Nanoscale Science and Engineering Center

Argonne National Laboratory

U.S. Department of Energy

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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