Bis-pyrazolone-based dysprosium(iii) complexes: zero-field single-molecule magnet behavior in the [2 × 2] grid DyIII4 cluster

Author:

Ashebr Tesfay G.123ORCID,Li Xiao-Lei1ORCID,Zhao Chen12ORCID,Yang Qianqian12,Tang Jinkui12ORCID

Affiliation:

1. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China

2. School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei 230026, P. R. China

3. Department of Industrial Chemistry, Addis Ababa Science and Technology University, P. O. Box, 16417, Addis Ababa, Ethiopia

Abstract

We report the magneto-structural details of two new dysprosium(iii) compounds obtained via multi-dentate pyrazolone-based hydrazone ligands, featuring a tetra-nuclear [2 × 2] grid and bi-nuclear defected helicate-like structures.

Funder

National Natural Science Foundation of China

Key Research Program of Frontier Science, Chinese Academy of Sciences

Chinese Academy of Sciences

National Science and Technology Planning Project

Natural Science Foundation of Jilin Province

China Postdoctoral Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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