Slow magnetic relaxation in a heteroleptic anilate-based DyIII metal–organic framework

Author:

Oggianu Mariangela1ORCID,Bertolotti Federica2ORCID,Manna Fabio13ORCID,Congiu Francesco4ORCID,Cappai Antonio4,Melis Claudio4ORCID,Concas Giorgio4ORCID,Avarvari Narcis3ORCID,Masciocchi Norberto2ORCID,Mercuri Maria Laura1ORCID

Affiliation:

1. Dipartimento di ScienzeChimiche e Geologiche, Università degli Studi di Cagliari, 09042 Monserrato, Italy

2. Dipartimento di Scienza e Alta Tecnologia&To.Sca.Lab., Università dell'Insubria, via Valleggio 11, 22100 Como, Italy

3. Univ Angers, CNRS, MOLTECH-ANJOU, SFR MATRIX, F-49000 Angers, France

4. Dipartimento di Fisica, Universitàdegli Studi di Cagliari, 09042 Monserrato, Italy

Abstract

A new family of heterolepticanilate-based lanthanide MOFs (LnIII = Tb, Dy, Ho) has been obtained via the ancillary ligand synthetic strategy. Although the three species are structurally isomorphous, only Dy-MOF exhibits SMM behaviour.

Funder

Fondazione di Sardegna

Centre National de la Recherche Scientifique

Universite Angers

Publisher

Royal Society of Chemistry (RSC)

Reference55 articles.

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3. Reversible tuning of luminescence and magnetism in a structurally flexible erbium–anilato MOF

4. Lanthanide Metal-Organic Framework Microrods: Colored Optical Waveguides and Chiral Polarized Emission

5. Lanthanide doped coordination polymers with tunable afterglow based on phosphorescence energy transfer

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