A(NH3)xFePS3 (A = Li, K): intercalated Fe thiophosphate via the liquid ammonia method-Reference-Cited by-同舟云学术

A(NH3)xFePS3 (A = Li, K): intercalated Fe thiophosphate via the liquid ammonia method

Published:2021 Issue:6 Volume:5 Page:2715-2723
ISSN:2052-1537
Container-title:Materials Chemistry Frontiers
language:en
Short-container-title:Mater. Chem. Front.

Author:

Feng Xiaojing¹²³⁴⁵,Guo Zhongnan¹²³⁴⁵^ORCID,Yan Xiaoxiao¹²³⁴⁵,Deng Jun⁶⁷⁸⁹¹⁰,Wu Dan¹²³⁴⁵,Zhang Zijing¹²³⁴⁵,Sun Fan¹²³⁴⁵,Yuan Wenxia¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. School of Chemistry and Biological Engineering

3. University of Science and Technology Beijing

4. Beijing 100083

5. China

6. Research & Development Center for Functional Crystals

7. Beijing National Laboratory of Condensed Matter Physics

8. Institute of Physics

9. Chinese Academy of Sciences

10. Beijing 100190

Abstract

The liquid ammonia method is shown to be an efficient route to co-intercalate alkali-metals and NH₃ molecules in between FePS₃ layers, to regulate the crystalline structure and magnetic properties without inducing the Fe vacancy.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Materials Science

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QM/D0QM00789G

Reference51 articles.

1. Uber die Darstellung und Eigenschaften von Hexathio- und Hexaselenohypodiphosphaten

2. Structural determination of some MPS3 layered phases (M = Mn, Fe, Co, Ni and Cd)

3. Weak Van der Waals Stacking, Wide-Range Band Gap, and Raman Study on Ultrathin Layers of Metal Phosphorus Trichalcogenides

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