Palladium-catalyzed asymmetric allylic alkylation (AAA) with alkyl sulfones as nucleophiles-Reference-Cited by-同舟云学术

Palladium-catalyzed asymmetric allylic alkylation (AAA) with alkyl sulfones as nucleophiles

Published:2021 Issue:31 Volume:12 Page:10532-10537
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Trost Barry M.¹²³⁴^ORCID,Jiao Zhiwei⁵⁶⁷⁸,Gholami Hadi¹²³⁴

Affiliation:

1. Departmentof Chemistry

2. Stanford University

3. Stanford

4. USA

5. School of Chemistry

6. Sun Yat-Sen University

7. Guangzhou 510275

8. China

Abstract

A variety of “hard” α-sulfonyl carbanions of aryl, heteroaryl and alkyl sulfones were successfully employed as nucleophiles in palladium-catalyzed asymmetric allylic alkylation with excellent enantioselectivities.

Funder

Tamaki Foundation

Ministry of Education of the People's Republic of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC02599F

Reference75 articles.

1. Asymmetric Transition Metal-Catalyzed Allylic Alkylations

2. Metal-Catalyzed Enantioselective Allylation in Asymmetric Synthesis

3. Iridium-Catalyzed Asymmetric Allylic Substitution Reactions

4. Enantioselective Formation of Quaternary Centers by Allylic Alkylation with First-Row Transition-Metal Catalysts

5. Pd Asymmetric Allylic Alkylation (AAA). A Powerful Synthetic Tool.

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